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Dipole-dipole interactions near interfaces

Authors: M. Urbakh; J. Klafter;

Dipole-dipole interactions near interfaces

Abstract

In this paper we investigate changes in the interaction between point dipoles embedded in a liquid near a nonmetallic interface when compared to the bulk liquid. The liquid is represented in the continuum approximation, in terms of a nonlocal dielectric function t(k,w), and we analyze the dependence of the dipoledipole interactionon the distance between thedipoles and between thedipoles and the boundary as well as on thedielectric parameters that characterize the interface region. Although the continuum framework does not explicitly include molecular level details, it enables the derivation of closed expressions that relate microscopic quantities to measurable observables such as dielectric functions.9-' * Continuum approximations and their modifications have been shown to be powerful in unraveling leading physical processes in complex systems. The electrostatic interaction energy between two dipoles is given by

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
27
Average
Top 10%
Top 10%
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