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Transition dipole moment of the .nu.3 band of CH3

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1994 Spain Publisher:American Chemical Society (ACS)Journal:The Journal of Physical Chemistry, volume 98, pages 5,862-5,866 (issn: 0022-3654, eissn: 1541-5740,

Authors: Tanarro, Isabel; Sanz, M.M.; Domingo, Concepción; Bermejo, Dionisio; Santos, Julio; Doménech, José Luis;

doi: 10.1021/j100074a009

handle: 10261/75377

Transition dipole moment of the .nu.3 band of CH3

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Abstract

The transition dipole moment of the ν3 band of the methyl radical has been measured for the first time. A new discharge laser amplitude double modulation method with a difference frequency laser spectrometer and a hollow cathode discharge cell has been used. The CH3 concentration has been estimated from the absorption decay when the discharge is turned off. The transition dipole moment is found to be μν3 = 0.029 ± 0.005 D. © 1994 American Chemical Society.

Financial support of the Spanish DGICYT (Project PB91-0128).

Peer Reviewed

Country

Spain

Related Organizations

Spanish National Research Council
Spain

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