
doi: 10.1021/ef900878u
The objectives of this work were to identify a practical accelerated oxidative stability test method and to define a reasonable, data-based, stability minimum requirement. The biodiesel (B100) samples show a broad distribution of stability on accelerated tests, with EN14112 induction time results ranging from less than 1 h to as much as 12 h and ASTM D2274 total insolubles ranging from less than 1 mg/100 mL to nearly 18 mg/100 mL. The accelerated test data indicate that if the B100 stability is above roughly a 3 h induction time, blends prepared from that B100 appear to be stable on the induction time and D2274 tests. The D4625 long-term storage results for B100 indicate that most biodiesel samples, regardless of initial induction time, will begin to oxidize immediately during storage. If induction time is near or below the 3 h limit, the B100 will most likely go out of specification for either stability or acid value within 4 months (4 weeks on the D4625 test). Even B100 with induction times longer than ...
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