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“Flash” Synthesis of CdSe/CdS Core–Shell Quantum Dots

Authors: Cirillo, Marco; Aubert, Tangi; Gomes, Raquel; Van Deun, Rik; Emplit, Philippe; Biermann, Amelie; Lange, Holger; +3 Authors

“Flash” Synthesis of CdSe/CdS Core–Shell Quantum Dots

Abstract

We report on the “flash” synthesis of CdSe/CdS core–shell quantum dots (QDs). This new method, based on a seeded growth approach and using an excess of a carboxylic acid, leads to an isotropic and epitaxial growth of a CdS shell on a wurtzite CdSe core. The method is particularly fast and efficient, allowing the controllable growth of very thick CdS shells (up to 6.7 nm in the present study) in no more than 3 min, which is considerably shorter than in previously reported methods. The prepared materials present state-of-the-art properties with narrow emission and high photoluminescence quantum yields, even for thick CdS shells. Additionally, Raman analyses point to an alloyed interface between the core and the shell, which, in conjunction with the thickness of the CdS shell, results in the observed considerable reduction of the blinking rate.

Country
Belgium
Keywords

nanocrystals, giant core/shell Raman, nonblinking, semiconductor, Optique non linéaire

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
131
Top 10%
Top 10%
Top 1%
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