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Radiation Chemistry of Polybutene-1

descriptionPublicationkeyboard_double_arrow_right Part of book or chapter of book 05 May 1996 Australia Publisher:American Chemical Society (ACS)

Authors: Busfield, W K; Watson, Gregory S;

doi: 10.1021/bk-1996-0620.ch005

handle: 10072/179403

Radiation Chemistry of Polybutene-1

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Abstract

Molecular weight changes and gel content measurements of moderately isotactic polybutene-1 following gamma irradiation at ambient temperature, show that both scission and crosslinking occur with G values of 3.2 and 1.0 respectively. 13C NMR shows there is also a loss of stereoregularity. The G value for the loss of isotactic pentads is 13.9, considerably less than that for polypropylene. Thus the amount of temporary chain scission is significantly less during the irradiation of polybutene-1 than with polypropylene. ; Griffith Sciences, School of Natural Sciences ; No Full Text

Country

Australia

Related Organizations

Griffith University
Australia
University of the Sunshine Coast
Australia

Keywords

FoR 0204 (Condensed Matter Physics), Flow analysis, FoR 0912 (Materials Engineering)

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