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Langmuir
Article
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MPG.PuRe
Article . 2018
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Langmuir
Article . 2018 . Peer-reviewed
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Langmuir
Article . 2018
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Adaptive Wetting—Adaptation in Wetting

Authors: Stefan A. L. Weber; Stefan A. L. Weber; Doris Vollmer; Hans-Jürgen Butt; Werner Steffen; Rüdiger Berger;

Adaptive Wetting—Adaptation in Wetting

Abstract

Many surfaces reversibly change their structure and interfacial energy upon being in contact with a liquid. Such surfaces adapt to a specific liquid. We propose the first order kinetic model to describe dynamic contact angles of such adaptive surfaces. The model is general and does not refer to a particular adaptation process. The aim of the proposed model is to provide a quantitative description of adaptive wetting and to link changes in contact angles to microscopic adaptation processes. By introducing exponentially relaxing interfacial energies and applying Young's equation locally, we predict a change of advancing and receding contact angles depending on the velocity of the contact line. Even for perfectly homogeneous and smooth surfaces, a dynamic contact angle hysteresis is obtained. As possible adaptations, we discuss changes and reconstruction of polymer surfaces or monolayers, diffusion and swelling, adsorption of surfactants, replacement of contaminants, reorientation of liquid molecules, or formation of an electric double layer.

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    99
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
99
Top 1%
Top 10%
Top 10%
Green
bronze