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Chemistry of Materials
Article . 2017
License: taverne
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Efficient and Stable Luminescence from Mn2+ in Core and Core–Isocrystalline Shell CsPbCl3 Perovskite Nanocrystals

Authors: Xiaobin Xie; Kunyuan Xu; Andries Meijerink; Chun Che Lin; Chun Che Lin;

Efficient and Stable Luminescence from Mn2+ in Core and Core–Isocrystalline Shell CsPbCl3 Perovskite Nanocrystals

Abstract

There has been a growing interest in applying CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) for optoelectronic application. However, research on doping of this new class of promising NCs with optically active and/or magnetic transition metal ions is still limited. Here we report a facile room temperature method for Mn2+ doping into CsPbCl3 NCs. By addition of a small amount of concentrated HCl acid to a clear solution containing Mn2+, Cs+, and Pb2+ precursors, Mn2+-doped CsPbCl3 NCs with strong orange luminescence of Mn2+ at ∼600 nm are obtained. Mn2+-doped CsPbCl3 NCs show the characteristic cubic phase structure very similar to the undoped counterpart, indicating that the nucleation and growth mechanism are not significantly modified for the doping concentrations realized (0.1 at. % - 2.1 at. %). To enhance the Mn2+ emission intensity and to improve the stability of the doped NCs, isocrystalline shell growth was applied. Growth of an undoped CsPbCl3 shell greatly enhanced the emission intensity of Mn2+ and resulted in lengthening the radiative lifetime of the Mn2+ emission to 1.4 ms. The core-shell NCs also show superior thermal stability and no thermal degradation up to at least 110 °C, which is important in applications.

Country
Netherlands
Keywords

Taverne

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
167
Top 1%
Top 10%
Top 1%
Green
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