
pmid: 12470731
The mechanism of thionitrite decomposition, both in vivo and in vitro, remains unclear. Thionitrite stability is highly variable; it is a complex function of thionitrite structure and environmental condition. Several recent advances clarify the role of unimolecular homlytic decomposition, metal-catalyzed reductive decomposition and higher-order enzymatic and non-enzymatic processes to the overall observed stability of thionitrites.
Nitric Oxide, Aldehyde Oxidoreductases, Oxygen, Kinetics, Drug Stability, Animals, Humans, Sulfhydryl Compounds, Oxidation-Reduction, Copper, Nitrites, Sulfur
Nitric Oxide, Aldehyde Oxidoreductases, Oxygen, Kinetics, Drug Stability, Animals, Humans, Sulfhydryl Compounds, Oxidation-Reduction, Copper, Nitrites, Sulfur
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