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Group Theory and Crystal Field Theory

Authors: Paul H. E. Meijer; Charles M. Herzfeld;

Group Theory and Crystal Field Theory

Abstract

Publisher Summary The chapter describes crystal field theory that concerns with an attempt to calculate as much as possible about the behavior of solids on the basis of a known or assumed symmetry of the problem and with the simplifying assumption that the interaction between the ion or atom of interest and its nearest neighbors is electrostatic in nature. Some recent group theoretical developments have made the application of group theoretical methods to solid state physics much more convenient. At the same time, physical problems have become much more complex. These two trends have combined to revive interest in group theoretical methods. Thus, it has seemed worthwhile to present the fundamental ideas of group theory and their application to crystal field theory from an advanced point of view, taking into account recent developments and problems. This chapter is on principles and theoretical methods, rather than results. Several topics of special relevance to crystal field theory are discussed—namely, time reversal and the Kramers theorem, and the Jahn-Teller theorem. With these preliminaries taken care of, the discussion of crystal field theory is straightforward.

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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    18
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
18
Average
Top 10%
Average
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