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Dipole moments of compounds containing a cobalttin bond

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1975Publisher:Elsevier BVJournal:Journal of Organometallic Chemistry, volume 97, pages 453-459 (issn: 0022-328X,

Authors: L.F. Wuyts; G.P. Van Der Kelen;

doi: 10.1016/s0022-328x(00)89311-0

Dipole moments of compounds containing a cobalttin bond

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Abstract

Abstract The molecular electric dipole moments are reported for the series of tin-substituted tetracarbonyl cobalt compounds R n Y m−n Sn{Co(CO) 4 } 4− m ( m = 1–3 ; n ⩽ m ; R = alkyl, phenyl; Y = halogen). The effect of the substituents at the tin atom on the nature of the CoSn bond is established on calculating the (CO) 4 CoSn group dipole moments. It is shown that the charge transfer in the CoSn bond is mainly determined by the inductive properties of the ligands attached to tin.

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Ghent University
Belgium

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