Synthesis and electrochemical properties of Li2S–B2S3–Li4SiO4

descriptionPublicationkeyboard_double_arrow_right Article 31 Oct 2006 English Publisher:Elsevier BVJournal:Solid State Ionics, volume 177, pages 2,601-2,603 (issn: 0167-2738,

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Authors: Y SEINO; K TAKADA; B KIM; L ZHANG; N OHTA; H WADA; M OSADA; +1 Authors

doi: 10.1016/j.ssi.2006.01.005

Synthesis and electrochemical properties of Li2S–B2S3–Li4SiO4

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Abstract

Abstract New Li + ion-conductive glasses Li 2 S–B 2 S 3 –Li 4 SiO 4 were synthesized by rapid quenching, and they were transformed into glass ceramics by heat treatment. The heat treatment increased the ionic conductivities of the Li 4 SiO 4 -doped glasses, and the highest ionic conductivity observed in the system was 1.0 × 10 − 3 S cm − 1 at room temperature. The glass ceramics were highly stable against electrochemical oxidation with a wide electrochemical window of 10 V.

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