Abstract A new monomer, N,N ′-bis(4-phenoxybenzoyl)- m -phenylenediamine (BPBMPD), was prepared by condensation of m -phenylenediamine with 4-phenoxybenzoyl chloride in N,N -dimethylacetamide (DMAc). Novel soluble aromatic poly(ether amide amide ether ketone ketone)s (PEAAEKKs) were synthesized by electrophilic Friedel–Crafts solution copolycondensation of BPBMPD with a mixture of terephthaloyl chloride (TPC) and isophthaloyl chloride (IPC) in the presence of anhydrous aluminum chloride and N -methylpyrrolidone (NMP) in 1,2-dichloroethane (DCE). The influences of reaction conditions on the preparation of polymers were examined. The polymers obtained were characterized by different physico-chemical techniques such as FT-IR, DSC, TGA, and wide-angle X-ray diffraction (WAXD). All the polymers were amorphous and the solubility of the polymers was improved by the incorporation of 1,3-dibenzoylaminobenzene moieties in the main chain. Thermal analyses showed that the polymers had high T g s of 220–231 °C and exhibited high thermal stability. All the polymers formed transparent, strong, and flexible films, with tensile strengths of 102.9–108.5 MPa, Young’s moduli of 2.44–2.86 GPa, and elongations at break of 9.8–13.7%.