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Abstract In this work, the effects of orientated crystal morphology of polypropylene (PP) induced by tensile stretching on the subsequent crystallization behavior of polybutene-1 (PB-1) in the incompatible PP/PB-1 (50/50) blends were studied. When the PP/PB-1 blends were stretched at a temperature above melting temperature (Tm) of PB-1 but below the Tm of PP, strong orientation of PP crystals was observed under stretching. As temperature dropped below Tm of PB-1, orientated form II and I′ of PB-1 appeared. In the framework of PP crystals, form I′ of PB-1 was formed due to the confined effect which suppressed the formation of form II crystals. Interfacial interaction played a role in guiding the nucleation of both form II and I’ crystals resulting in highly oriented structures. The mechanism of PB-1 orientation and confined crystallization under stretching in PP/PB-1 (50/50) blends was discussed.
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 14 | |
popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 10% | |
influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |