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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Polymerarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Polymer
Article . 2012 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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LCST and UCST behavior in polymer solutions and blends

Authors: E.A. Clark; J.E.G. Lipson;

LCST and UCST behavior in polymer solutions and blends

Abstract

Abstract We introduce a model for polymer solutions and blends that display both an upper and a lower critical solution temperature (UCST, LCST). Using our simple analytic lattice theory along with a fixed parameter set independent of both composition and temperature, we study solutions and blends exhibiting complicated miscibility patterns, including cases in which a UCST is below an LCST, or above. With respect to the former, we examine the conditions under which a so-called hourglass phase diagram may evolve. Where possible we compare directly with experiment, however, we also explore the behaviour of a number of hypothetical solutions and blends. One experimental solution of particular interest comprises star polystyrene (PS) and cyclohexane; in this case we supply what we believe are the only measured pressure-volume-temperature data for a high molecular weight (5.2 × 105 g/mol) star PS.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
78
Top 1%
Top 10%
Top 10%
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