Biotransformation of bromosesquiterpenes by marine fungi

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 2009 English Publisher:Elsevier BVJournal:Phytochemistry, volume 70, pages 2,023-2,026 (issn: 0031-9422,

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Authors: Masahiro, Koshimura; Takamitsu, Utsukihara; Mai, Kawamoto; Michihiko, Saito; C Akira, Horiuchi; Masayuki, Kuniyoshi;

doi: 10.1016/j.phytochem.2009.08.021

pmid: 19772936

Biotransformation of bromosesquiterpenes by marine fungi

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Abstract

Biotransformation of bromosesquiterpenes was investigated with two types of fungi, Rhinocladiella atrovirens NRBC 32362 and also Rhinocladiella sp. K-001, isolated from the Okinawan brown alga Stypopodium zonale. R. atrovirens NRBC 32362 converted aplysistatin 1 into three compounds 5alpha-hydroxyaplysistatin 4, 5alpha-hydroxyisoaplysistatin 5 and 9beta-hydroxyaplysistatin 6. Transformation of 1, palisadin A 2 and 12-hydroxypalisadin B 3 by Rhinocladiella sp. K-001 gave two compounds, 3,4-dihydroaplysistatin 7 and 9,10-dehydrobromopalisadin A 8.

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Keywords

Bromine Compounds, Phaeophyceae, Plant Extracts, Fungi, Laurencia, Sesquiterpenes, Biotransformation

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