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Physica A Statistical Mechanics and its Applications
Article . 2004 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2021
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
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Derivation of the Onsager principle from large deviation theory

Authors: La Cour, Brian R.; Schieve, William C.;

Derivation of the Onsager principle from large deviation theory

Abstract

The Onsager linear relations between macroscopic flows and thermodynamics forces are derived from the point of view of large deviation theory. For a given set of macroscopic variables, we consider the short-time evolution of near-equilibrium fluctuations, represented as the limit of finite-size conditional expectations. The resulting asymptotic conditional expectation is taken to represent the typical macrostate of the system and is used in place of the usual time-averaged macrostate of traditional approaches. By expanding in the short-time, near-equilibrium limit and equating the large deviation rate function with the thermodynamic entropy, a linear relation is obtained between the time rate of change of the macrostate and the conjugate initial macrostate. A Green-Kubo formula for the Onsager matrix is derived and shown to be positive semi-definite, while the Onsager reciprocity relations readily follow from time reversal invariance. Although the initial tendency of a macroscopic variable is to evolve towards equilibrium, we find that this evolution need not be monotonic. The example of an ideal Knundsen gas is considered as an illustration.

25 pages, 3 figures

Keywords

Statistical Mechanics (cond-mat.stat-mech), FOS: Physical sciences, Condensed Matter - Statistical Mechanics

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Average
Average
Average
Green
bronze