Chemiluminescence in decomposition of bridged 1,2,4,5-tetraoxanes catalyzed by ferrocene

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 2017 English Publisher:OOO Zhurnal "Mendeleevskie Soobshcheniya"Journal:Mendeleev Communications, volume 27, pages 371-373 (issn: 0959-9436,

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Authors: Dim I. Galimov; Dilara R. Gazeeva; Ramil G. Bulgakov; Alexander O. Terent’ev;

doi: 10.1016/j.mencom.2017.07.017

Chemiluminescence in decomposition of bridged 1,2,4,5-tetraoxanes catalyzed by ferrocene

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Abstract

Chemiluminescence was observed in ferrocene-catalyzed decomposition of bridged 1,2,4,5-tetraoxanes, namely, 2,3,5,6-tetraoxabicyclo[2.2.1]heptanes. The chemi- and photoluminescence spectra revealed the main products and luminescence emitters to be β-diketones. The reaction intermediate, the OOH radical, was found to catalyze the decomposition of the 1,2,4,5-tetraoxanes.

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Russian Academy of Sciences
Russian Federation

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