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Journal of Magnetic Resonance
Article . 2011 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Radiation damping on cryoprobes

Authors: Shishmarev, Dmitry; Otting, Gottfried;

Radiation damping on cryoprobes

Abstract

Radiation damping on 600 and 800 MHz cryoprobes was investigated. The phase angle β between a vector 90° phase shifted to the precessing magnetization and the rf field induced in the coil was found to depend markedly on whether an FID was being acquired or not. The magnitude of the radiation damping field was sufficiently strong to restore 95% of the equilibrium water magnetization of a 90% H2O sample in a 5 mm sample tube within about 5 ms following a 165° pulse. This can be exploited in water flip-back versions of NOESY and TOCSY experiments of proteins, but care must be taken to limit the effect of the radiation damping field from the water on the Ha protons. Long water-selective pulses can be applied only following corrections. We developed a program for correcting pulse shapes if β is non-zero. The WATERGATE scheme is shown to be insensitive to imperfections introduced by radiation damping.

Country
Australia
Related Organizations
Keywords

RF fields, Magnetic Resonance Spectroscopy, Radio Waves, dimethyl sulfoxide, WATERGATE, 2 propanol, Water flip-back, Damping, Magnetization, dyes, Keywords: Cryoprobe, 2-Propanol, Radiation damping, Electromagnetic Fields, TOCSY, Dimethyl Sulfoxide, Pulse shapes, Phase angles, Carbon Isotopes, Radiation, carbon, reagents, w Cryoprobe, Reproducibility of Results, Water, indicators, Phase shifted, Cold Temperature, markers and buffers, Indicators and Reagents, Sample tube, Protons, Algorithms, NOESY, proton

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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
18
Top 10%
Average
Top 10%
Green