
Exact knowledge of the dead time as part of the bubble lifetime in the maximum bubble pressure method is an important prerequisite for accurate dynamic surface tension measurements. The duration of the dead time depends essentially on the capillary geometry and affects significantly the measured surface tensions of concentrated surfactant solutions. Increase of the dead time leads to a significant surface tension decrease of a freshly formed bubble surface due to the significantly higher residual adsorption of the surfactant molecules. It is shown that correct dynamic surface tensions are obtained with the experimental procedure of Sugden's method only when in addition to the fixed frequency of bubble formation, also the dead time values for the two capillaries are kept constant.
Solutions, Surface-Active Agents, Time Factors, Surface Properties, Pressure, Surface Tension, Adsorption, Particle Size, Sensitivity and Specificity, Chromatography, High Pressure Liquid
Solutions, Surface-Active Agents, Time Factors, Surface Properties, Pressure, Surface Tension, Adsorption, Particle Size, Sensitivity and Specificity, Chromatography, High Pressure Liquid
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