Chloride-substitution in sodium borohydride

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 2011 English Publisher:Elsevier BVJournal:Journal of Alloys and Compounds, volume 509, pages L228-L231 (issn: 0925-8388,

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Authors: Jørn Eirik Olsen; Magnus H. Sørby; Bjørn C. Hauback;

doi: 10.1016/j.jallcom.2011.03.166

Chloride-substitution in sodium borohydride

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Abstract

Abstract The changes in structure and stability of NaBH4 on Cl-substitution obtained in mechanochemical reactions between NaBH4 and NaCl have been investigated by conventional and synchrotron radiation powder X-ray diffraction, differential scanning calorimetry and temperature programmed desorption. Powder X-ray diffraction shows an apparent full homogeneity range between NaBH4 and NaCl, giving Na(BH4)1−xClx phase where x corresponds to the ratios of the initial reagents. Differential scanning calorimetry indicates that the Cl-substitution stabilizes the product, by increasing temperature for melting and desorption.

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Institute for Energy Technology
Norway

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