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Geochimica et Cosmochimica Acta
Article
License: CC BY NC ND
Data sources: UnpayWall
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Geochimica et Cosmochimica Acta
Article . 2016 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Determination of aragonite trace element distribution coefficients from speleothem calcite–aragonite transitions

Authors: Wassenburg, J.A.; Scholz, D.; Jochumb, K.P.; Cheng, H.; Ostere, J.; Immenhauser, A.; Richter, D.K.; +5 Authors

Determination of aragonite trace element distribution coefficients from speleothem calcite–aragonite transitions

Abstract

The processes that govern the incorporation of (trace) elements into speleothems can often be linked to environmental changes. Although element incorporation into speleothem calcite is now reasonably well understood, current knowledge regarding trace element variability in speleothem aragonite is very limited. Of particular interest is whether trace element distribution coefficients are above or below one in order to assess the extent to which prior aragonite precipitation has affected speleothem aragonite trace element records. This study uses nine calcite-to-aragonite transitions in seven speleothems from diverse environmental settings to derive the first quantitative estimates of the distribution coefficients for several elements in speleothem aragonite: DMg(Ar) = 9.7E-5 ± 9.01E-5, DBa(Ar) = 0.91 ± 0.88, DSr(Ar) = 1.38 ± 0.53, and DU(Ar) = 6.26 ± 4.54 (1s SD). For one speleothem from westernGermany, the distribution coefficients are generally higher, which is potentially related to the very low growth rates (<11 µm/year) of this sample. In particular, DSr(Ar) appears to show a negative correlation with growth rate when growth rate is below 20 µm/year. In summary, our results demonstrate that speleothem aragonite DMg(Ar) is below one, DU(Ar) is considerably above one, and DSr(Ar) is above one or close to unity. For DBa(Ar), reaching a similar conclusion is difficult due to the relatively high uncertainty. Enhanced prior aragonite precipitation will thus result in lower U and higher Mg concentrations in speleothem aragonite, although in many cases Mg in speleothem aragonite is most likely dominated by other processes. This result suggests that U concentrations in aragonitic stalagmites could serve as a very effective proxy for palaeo-rainfall.

Countries
United Kingdom, United States
Keywords

550, Cave, F700, F800, 910, F600, Speleothem, 530, F900, Aragonite, Distribution Coefficient, Trace Element

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
70
Top 10%
Top 10%
Top 10%
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