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Electrochimica Acta
Article
License: CC BY NC ND
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Electrochimica Acta
Article . 2015 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Rules to transform concentrations and currents for irreversible reactions to those of quasireversible reactions

Authors: David A. Harrington;

Rules to transform concentrations and currents for irreversible reactions to those of quasireversible reactions

Abstract

Abstract Transformation rules are given that take the concentration or current expressions for the simple irreversible electron-transfer reaction R → P + e − and convert them to the corresponding quantities for the quasireversible reaction. They apply for many standard electrochemical mass-transport cases, including simple diffusion and convection-diffusion for the rotating disk or channel flow, provided that the diffusivities of the two species are equal. The forward rate constant is replaced by the sum of the forward and reverse rate constants, the result is scaled and then a constant added. Rules are also given for some cases where the diffusivities are unequal. As an application, a new solution of the concentration profile for a channel electrode within the Leveque approximation neglecting axial diffusion is given.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Average
Average
Average
hybrid