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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Electrochimica Actaarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Electrochimica Acta
Article . 2013 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Effect of uncompensated solution resistance on quasireversible charge transfer at rough and finite fractal electrode

Authors: Rama Kant; M. Sarathbabu; Shruti Srivastav;

Effect of uncompensated solution resistance on quasireversible charge transfer at rough and finite fractal electrode

Abstract

Abstract Theory for the influence of uncompensated solution resistance on quasi-reversible charge transfer at an arbitrary rough electrode is developed. Detailed model analysis is performed for a finite fractal power spectrum; characterized with fractal dimension, lowest, highest cutoff-length scales of roughness and topothesy length (width) of the interface. The composite effect of the real and apparent kinetics is contained in LHΩ which is summation of diffusion-kinetics (LH) and diffusion-ohmic (LΩ) coupling lengths. The current time response is therefore an interplay of LHΩ, diffusion length, three finite fractal lengths and fractal dimension (manifesting themselves at different times). At short time, diffusion length is smaller than LHΩ, current is proportionate to the ratio of real microscopic area and LHΩ. These phenomenological coupling delays and curtails the onset of the anomalous response. As diffusion length becomes greater than LHΩ, there is an emergence of intermediate anomalous region. However, limiting case of large LHΩ approximately constant current is seen, without dynamic roughness effects.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
23
Top 10%
Top 10%
Top 10%
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