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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Electrochimica Actaarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Electrochimica Acta
Article . 2009 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Crevice corrosion cathodic reactions and crevice scaling laws

Authors: Glyn F. Kennell; Richard W. Evitts;

Crevice corrosion cathodic reactions and crevice scaling laws

Abstract

A numerical model that predicts the rates of metal dissolution and electrolyte composition along the length of a metallic crevice was used to simulate the crevice corrosion of AISI 304 stainless steel. The model considers both the forward and reverse electrochemical reactions that might take place during the corrosion process. The environment exterior to the crevice, where a net cathodic current is produced, was simultaneously modeled. It was found that cathodic reactions are likely to occur towards the tip of the crevice. For the case when the hydrogen evolution reaction was considered as a possible cathodic reaction in the crevice, it is shown how the delayed instigation of this reaction may be the cause of an experimentally observed increase in pH at the crevice tip. Two critical crevice scaling laws were examined using model predictions and one scaling law fit the model predictions very well. This scaling law differentiates between crevices that will undergo active corrosion and those that will remain indefinitely passive.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
31
Top 10%
Top 10%
Top 10%
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