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Electrochemistry Communications
Article . 2015 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Borohydride electro-oxidation on Pt single crystal electrodes

Authors: Valentín Briega-Martos; Enrique Herrero; Juan M. Feliu;

Borohydride electro-oxidation on Pt single crystal electrodes

Abstract

The borohydride oxidation reaction on platinum single-crystal electrodes has been studied in sodium hydroxide solution using static and rotating conditions. The results show that borohydride electro-oxidation is a structure sensitive process on Pt surfaces. Significant changes in the measured currents are observed at low potentials. In this region, the Pt(111) electrode exhibits the lowest activity, whereas the highest currents are measured for the Pt(110) electrode. The behavior of the different electrodes is discussed taking as reference the observed behavior on the blank electrolyte and the possible formation of weakly adsorbed intermediates.

This work has been financially supported by the MICINN (Spain) (project 2013-44083-P) and Generalitat Valenciana (project PROMETEOII/2014/013).

Related Organizations
Keywords

Single crystal electrodes, Surface sensitive, Fuel cell, Borohydride oxidation, Química Física, Platinum

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
28
Top 10%
Top 10%
Top 10%
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