
By removing complications caused by transport, the surface confinement of substrate and product members of a redox pair simplifies the relationships governing transient electrode reactions, often permitting a mathematical solution even when the voltammetry is kinetically controlled. Here a non-simulative study is undertaken and applied to linear-potential-scan chronoamperometry and cyclic voltammetry. Exact equations are rederived for reversible and irreversible cases; novel quasireversible results are in the form of integrals that may be evaluated numerically.
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| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |
