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Electrochemistry Communications
Article . 2005 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Quasireversible cyclic voltammetry of a surface confined redox system: a mathematical treatment

Authors: Jan C. Myland; Keith B. Oldham;

Quasireversible cyclic voltammetry of a surface confined redox system: a mathematical treatment

Abstract

By removing complications caused by transport, the surface confinement of substrate and product members of a redox pair simplifies the relationships governing transient electrode reactions, often permitting a mathematical solution even when the voltammetry is kinetically controlled. Here a non-simulative study is undertaken and applied to linear-potential-scan chronoamperometry and cyclic voltammetry. Exact equations are rederived for reversible and irreversible cases; novel quasireversible results are in the form of integrals that may be evaluated numerically.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
58
Top 10%
Top 10%
Top 10%
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