Linear free-energy relationship

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 2006 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 421, pages 464-468 (issn: 0009-2614,

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Authors: O.A. Khakhel’;

doi: 10.1016/j.cplett.2006.01.084

Linear free-energy relationship

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Abstract

Abstract It is shown that a nature of the LFER phenomenon is related to phase volumes of the system’s states, for which a difference of free energy is determined. An invariability of these volumes is the single factor generating the LFER phenomenon. As an example, the LFER manifestations for an intramolecular excimer formation with 1,3-di(1pyrenyl)propane in various solvents are analyzed.

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National Academy of Sciences of Ukraine
Ukraine

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