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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Chemical Physicsarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Chemical Physics
Article . 2006 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Green’s function calculation of radical pair recombination: I. Gyroscopic model formalism

Authors: A.B. Doktorov; J. Boiden Pedersen;

Green’s function calculation of radical pair recombination: I. Gyroscopic model formalism

Abstract

Abstract A general gyroscopic model description of radical pair recombination in high magnetic fields is formulated. Recombination is allowed to occur simultaneously from the singlet and triplet states. The description is valid for any diffusion model, symmetry of the system, and exchange interaction, as well as for any rate of recombination, dephasing, intra-radical relaxation, and singlet–triplet mixing. By use of Green’s function technique we derive general fundamental expressions for the stationary recombination probability for spherical symmetric systems with contact recombination. These general expressions can be applied to a wide class of radical pair systems and they form an exact foundation for development of systematic and consistent approximation schemes. It is shown that the recombination and escape yields for any combination of reactive channels and precursor spin states can be calculated from the singlet recombination yield for a triplet precursor. The general results are applied to a locally weak exchange interaction and explicit expressions are derived for the recombination probability in terms of contact values of the Green’s function for the relative motion of the radical partners. The resulting expressions can be adopted to experimental situations by inserting the required values for the adopted diffusion model.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Top 10%
Average
Average
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