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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Chemical Engineering...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Chemical Engineering Science
Article . 2015 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Mass–count plots for crystal size control

Authors: Daniel J. Griffin; Martha A. Grover; Yoshiaki Kawajiri; Ronald W. Rousseau;

Mass–count plots for crystal size control

Abstract

Abstract We present measurements from batch crystallization as a trajectory in the phase space mapped out by the crystal mass and the total chord count. This new perspective yields a framework for monitoring and controlling crystallization that has two beneficial attributes: first, crystallization is seen as movement—we find that this fosters an intuitive understanding of crystallization kinetics; and, second, the problem of controlling the average crystal size is cast as a trajectory-endpoint control problem—we find that this promotes the development of spatially-oriented control schemes. The utility of the proposed framework is demonstrated by application. In particular, we apply the framework to: 1) elucidate the effects of simple temperature manipulations on the crystallization kinetics; 2) interpret the actions applied by supersaturation control (SSC) and direct nucleation control (DNC) to produce large crystals; and 3) develop a control scheme—termed spatially-guided action trajectory endpoint control (sGATEC)—that can be applied to produce crystals of pre-selected average size.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
13
Top 10%
Average
Average
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