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Chemical Engineering Science
Article . 2006 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Modeling on the kinetics of an EPDM devulcanization in an internal batch mixer using an amine as the devulcanizing agent

Authors: Sutanto, P.; Laksmana, F. L.; Picchioni, E.; Janssen, L. P. B. M.; Picchioni, F.;

Modeling on the kinetics of an EPDM devulcanization in an internal batch mixer using an amine as the devulcanizing agent

Abstract

The use of amines and the application of mechanical force (shear) in rubber devulcanization have been reported in the literatures. In this paper, the devulcanization of ethylene propylene diene rubber (EPDM) is conducted in a Brabender batch mixer using hexadecylarnine (HDA) as the devulcanizing agent. Considering the complexity of the compound and the limitations of the analyses techniques for crosslinked systems, an engineering approach to model a devulcanization process of EPDM material is proposed. An engineering kinetic model has been derived by fitting a large number of experimental data with several models based on simple kinetic considerations. Rate determining parameters such as temperature, shear rate, reactant concentrations and time are included in the model. The model obtained covers all the phenomena happening during the devulcanization, without distinguishing them on the molecular level. (c) 2006 Elsevier Ltd. All rights reserved.

Country
Netherlands
Related Organizations
Keywords

computation, modelling, kinetics, rubber, RUBBER, processing, recycling

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    55
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    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
55
Top 10%
Top 10%
Average
bronze