Abstract Ladle furnace slag (LFS), a by-product of the steel making process, was tested for its potential use as a supplementary cementing material. The material used for the tests was screened or ground, producing three samples of different fineness, and the granulometry of these LFS samples was also tested by particle size analysis. Their chemical and mineralogical composition was assessed by chemical analysis, X-ray diffraction and thermogravimetric analysis. Finally, in order to determine the cementitious and pozzolanic character of LFS in relation to its granulometry, slag–lime and slag–cement mortars were produced and tested in compression. The results show that although LFS is a weak supplementary cementing material, it shows some self-cementing and pozzolanic properties that can be enhanced by screening or grinding the raw material. Even though different levels of fineness and granulometry can be reached with each method, generally, grinding seems to improve LFS binding properties more than sieving.