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Catalysis Communications
Article . 2019 . Peer-reviewed
License: Elsevier TDM
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https://dx.doi.org/10.1016/j.c...
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Thermally activated delayed fluorescence (TADF) dyes as efficient organic photosensitizers for photocatalytic water reduction

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2019 English Publisher:Elsevier BVJournal:Catalysis Communications, volume 119, pages 11-15 (issn: 1566-7367, Copyright policy )
Authors: Zhe-Jian Yu; Wen-Ya Lou; Henrik Junge; Ayla Päpcke; Hao Chen; Liang-Min Xia; Bin Xu; +7 Authors

doi: 10.1016/j.catcom.2018.09.018

Thermally activated delayed fluorescence (TADF) dyes as efficient organic photosensitizers for photocatalytic water reduction

Abstract

Abstract An efficient water reduction system was developed using thermally activated delayed fluorescence (TADF) dyes as organic photosensitizers and a palladium complex as water reduction catalyst. 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene (4CzIPN) that has the best fluorescence efficiency displayed the highest photoinduced productivity (TON up to 2567) and was active for 5 days. Based on time-resolved photoluminescence experiments on the photocatalytic system, reductive quenching of the TADF dye was found as main pathway occurring before intersystem crossing takes place.

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Top 10%
Average
Top 10%
gold
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