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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Biophysical Chemistr...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Biophysical Chemistry
Article . 2004 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Crystallization kinetics of homopolymers: overall crystallization: a review

Authors: Leo, Mandelkern;

Crystallization kinetics of homopolymers: overall crystallization: a review

Abstract

This paper is a brief review of the overall crystallization kinetics of synthetic homopolymers. The basic experimental results are presented and compared with theory that is currently available. It is found, surprisingly, that the more sophisticated theories do no better in explaining experimental results than does the free-growth approximation. This is contrary to what is observed for the crystallization of low molecular weight substances. The reason can be attributed to entanglements and other topological defects that are present in the pure melt and are relegated to the non-crystalline regions as crystallization progresses. This results in a more protracted crystallization than is predicted and is yet to be included in theory.

Related Organizations
Keywords

Kinetics, Polymers, Crystallization

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Top 10%
Top 10%
Average
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