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Luminescence of the Sb3+ ion in calcium fluorapatite and other phosphates

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1988 English Publisher:Elsevier BVJournal:Materials Chemistry and Physics, volume 19, pages 357-368 (issn: 0254-0584,

Authors: G. Blasse; W.M.A. Smit; E.W.J.L. Oomen;

doi: 10.1016/0254-0584(88)90097-1

Luminescence of the Sb3+ ion in calcium fluorapatite and other phosphates

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Abstract

Abstract Luminescence spectra and decay times of Sb 3+ in AlPO 4 , LaPO 4 , LiLaP 4 O 12 and calcium fluorapatite (Ca 10 (PO 4 ) 6 F 2 ) are reported. The luminescence properties of Sb 3+ in AlPO 4 , LaPO 4 and LiLaP 4 O 12 are explained by using existing models. The luminescence properties of Sb 3+ in calcium halophosphate have been reported before, but were not completely understood. We find that a strong Jahn-Teller interaction is working on the relaxed excited state of the Sb 3+ ion from which the luminescence properties can be explained. Evidence is given that Sb 3+ in calcium fluorapatite occupies a Ca 2+ site.

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