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Mixed anionic conduction in PbFCl

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1973 English Publisher:Elsevier BVJournal:Solid State Communications, volume 13, pages 677-679 (issn: 0038-1098,

Authors: J. Schoonman; A.F. Halff; G. Blasse;

doi: 10.1016/0038-1098(73)90457-2

Mixed anionic conduction in PbFCl

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Abstract

Abstract We have measured transference numbers of fluoride ions and chloride ions in undoped and doped samples of PbFCl. The results indicate pure anionic conduction. The electrical conductivity of doped single crystals support the assumption that the thermal defects in PbFCl are of the Schottky-type. The defect chemistry of PbFCl involved is described.

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