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Luminescence of the Te4+ ion in ZrP2O7

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1989 English Publisher:Elsevier BVJournal:Journal of Solid State Chemistry, volume 83, pages 361-365 (issn: 0022-4596,

Authors: M.J. den Exter; H. Donker; W.M.A. Smit; G. Blasse;

doi: 10.1016/0022-4596(89)90186-2

Luminescence of the Te4+ ion in ZrP2O7

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Abstract

The luminescence spectra and decay times of the Te{sup 4+} ion in ZrP{sub 2}O{sub 7} are reported and discussed. ZrP{sub 2}O{sub 7}:Te{sup 4+} shows a blue emission band with a maximum at 21,200 cm{sup {minus}1} at LHeT. Decay time measurements reveal the presence of at least two kinds of Te{sup 4+} ions. This is not apparent from the luminescence spectra, indicating that the Te{sup 4+} ions have quite similar environments. The {sup 1}S{sub 0} {yields} {sup 3}P{sub 1} excitation band of the Te{sup 4+} ion is situated at 38,250 cm{sup {minus}1}. A comparison is made with the luminescence of related systems.

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