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Abstract Vibrational and electronic spectra of compositions Ba 2 Mg 1− x Li 0.8 x W 1+0.2 x O 6 and Sr 1+ x La 1− x Li 1−0.2 x W 1+0.2 x O 6 are reported. The vibrational spectra show the presence of clusters of WO 6- 6 octahedra. Large clusters quench the luminescence that has been found for the compositions with x = 0.
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