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Vibrational spectra and structural considerations of compounds NaLnTiO4

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1974 Netherlands English Publisher:Elsevier BVJournal:Journal of Solid State Chemistry, volume 10, pages 206-210 (issn: 0022-4596,

Authors: Blasse, G.; Heuvel, G.P.M. van den;

doi: 10.1016/0022-4596(74)90027-9

Vibrational spectra and structural considerations of compounds NaLnTiO4

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Abstract

The Raman and infrared spectra of compounds NaLnTiO4 (Ln = lanthanide, including yttrium) are reported and discussed. Their most striking feature is a strong band in both spectra at about 900 cm−1. This band is ascribed to a vibration localized in the TiO bond directed towards the NaO layers. The relevant oxygen anion is very poorly charge compensated, and the TiO bond is, therefore, very strong. Pauling's electrostatic valence rule appears to be of great use in these considerations. These compounds do not show ferroelectricity.

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Netherlands

Related Organizations

Utrecht University
Netherlands
United States Department of the Interior
United States
University Museum Utrecht
Netherlands

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