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The nitrate symmetry in metallic nitrates

Name: The nitrate symmetry in metallic nitrates
Creator: John R. Ferraro
Keywords: 3. Good health

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1960 English Publisher:Elsevier BVJournal:Journal of Molecular Spectroscopy, volume 4, pages 99-105 (issn: 0022-2852,

Authors: John R. Ferraro;

doi: 10.1016/0022-2852(60)90071-0

The nitrate symmetry in metallic nitrates

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Abstract

Abstract An examination of the infrared spectra of metallic nitrates has shown that in progressing from a monovalent metallic nitrate to a tetravalent metallic nitrate and increased lowering of the nitrate symmetry, and a transition from a point group D3h symmetry to a point group C2v symmetry occurs. The degree of dissymmetry arising in these nitrates appears to be related in part to the ionic potential of the cation.

Related Organizations

Argonne National Laboratory
United States

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