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The luminescence of Pb2+ in alkaline earth sulfates

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 1995 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 246, pages 135-138 (issn: 0009-2614,

Authors: H.F. Folkerts; M.A. Hamstra; G. Blasse;

doi: 10.1016/0009-2614(95)01067-j

The luminescence of Pb2+ in alkaline earth sulfates

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Abstract

Abstract The luminescence properties of CaSO 4 :Pb 2+ (anhydrite), BaSO 4 :Pb 2+ , SrSO 4 :Pb 2+ and PbSO 4 (all barite) are reported. Pb 2+ -doped anhydrite shows Pb 2+ luminescence with a remarkably small Stokes shift to the emission. The barites, however, show emission with a much larger Stokes shift. It is argued that the Pb 2+ luminescence in these compounds is not due to pure s ↔ p transitions on the Pb 2+ ion.

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Utrecht University
Netherlands

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