Vibronic transitions in the excitation spectrum of the trivalent praseodymium ion

Name: Vibronic transitions in the excitation spectrum of the trivalent praseodymium ion
Keywords: 3. Good health

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1991 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 183, pages 367-371 (issn: 0009-2614,

Authors: G. Blasse; C. de Mello Donegá;

doi: 10.1016/0009-2614(91)90395-p

Vibronic transitions in the excitation spectrum of the trivalent praseodymium ion

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Abstract

Abstract Strong vibronic features in the excitation spectra of Pr 3+ in several compounds are reported. The observed vibronic lines belong to electronic transitions with Δ J =2 and Δ J =4. The last case violates existing theories. The intensity of the vibronic lines depends strongly on the host lattice. There are indications that the vibronic intensity depends also on the Pr 3+ concentration.

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