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Comparison of 7FJ←5DO emission spectra for Eu(III) in crystalline environments of octahedral, near-octahedral, and trigonal symmetry

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1983Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 95, pages 507-512 (issn: 0009-2614,

Authors: David Foster; Frederick S. Richardson; Andrew F. Kirby;

doi: 10.1016/0009-2614(83)80342-x

Comparison of 7FJ←5DO emission spectra for Eu(III) in crystalline environments of octahedral, near-octahedral, and trigonal symmetry

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Abstract

Abstract Isotropic 7FJ←5DO emission spectra are reported for Eu(III) in four different crystalline system. These systems differ with respect to Eu(III) site symmetry, coordination number, coordination geometry, and the chemical nature of the coordinated ligands. Comparison between the spectra obtained on these systems reveal major differences in the relative intensities of the 7FJ←5DO emission, and these differences are discussed in terms of ligand modulated 4f — 4f intensity mechanism.

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University of Virginia
United States

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