descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1975 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 36, pages 111-113 (issn: 0009-2614,

Authors: Hair, J.Th.W. de; Blasse, G.;

doi: 10.1016/0009-2614(75)85699-5

The nature of the emission transition of the octahedral uranate group

- Summary
- Subjects
- Metrics

Abstract

Decay times of the green luminescence of U6+ in oxides with perovskite structure are reported. The influence of the site symmetry is found to be considerable. The temperature dependence of the decay time gives evidence for a coupling of the electronic transition with a phonon of about 200 cm−1 in the excited state. The results show the emission to originate from a parity-forbidden transition, vibronically allowed by coupling with vibrations of ungerade symmetry.

Related Organizations

Utrecht University
Netherlands
University Museum Utrecht
Netherlands

Keywords

Scheikunde

Impact byBIP!

	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	17
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%