On the formation of reductic acid from pentoses or hexuronic acids

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1993 English Publisher:Elsevier BVJournal:Carbohydrate Research, volume 247, pages 217-222 (issn: 0008-6215,

Authors: Kjell Olsson; Eric Westerlund; Tania Ahmad; Rolf Andersson;

doi: 10.1016/0008-6215(93)84254-4

On the formation of reductic acid from pentoses or hexuronic acids

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Abstract

Abstract Careful hydrolysis of (±)- cis - or (±)- trans -tetrahydro-2,5-dimethoxy-2-furaldehyde dimethyl acetal proceeded via 5,5-dimethoxy-4-oxopentanal to give (±)- trans -4-hydroxy-5-methoxy-2-cyclopentenone and (±)- trans -4,5-dihydroxy-2-cyclopentenone. The latter product did not isomerize to 2,3-dihydroxy-2-cyclopentenone (reductic acid) on prolonged reaction.

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Swedish University of Agricultural Sciences
Sweden

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