In this paper, an efficient algorithm is established for computing the maximum (minimum) angular separation ρ max(ρ min), the corresponding apparent position angles ( $\theta|_{\rho_{\rm max}}$ , $\theta|_{\rho_{\rm min}}$ ) and the individual masses of visual binary systems. The algorithm uses Reed’s formulae (1984) for the masses, and a technique of one-dimensional unconstrained minimization, together with the solution of Kepler’s equation for $(\rho_{\rm max}, \theta|_{\rho_{\rm max}})$ and $(\rho_{\rm min}, \theta|_{\rho_{\rm min}})$ . Iterative schemes of quadratic coverage up to any positive integer order are developed for the solution of Kepler’s equation. A sample of 110 systems is selected from the Sixth Catalog of Orbits (Hartkopf et al. 2001). Numerical studies are included and some important results are as follows: (1) there is no dependence between ρ max and the spectral type and (2) a minor modification of Giannuzzi’s (1989) formula for the upper limits of ρ max functions of spectral type of the primary.