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Thermodynamics and Rate Thermodynamics

Thermodynamics and rate thermodynamics
Authors: Grmela, Miroslav;

Thermodynamics and Rate Thermodynamics

Abstract

Approach of mesoscopic state variables to time independent equilibrium sates (zero law of thermodynamics) gives birth to the classical equilibrium thermodynamics. Approach of fluxes and forces to fixed points (equilibrium fluxes and forces) that drive reduced mesoscopic dynamics gives birth to the rate thermodynamics that is applicable to driven systems. We formulate the rate thermodynamics and dynamics, investigate its relation to the classical thermodynamics, to extensions involving more details, to the hierarchy reformulations of dynamical theories, and to the Onsager variational principle. We also compare thermodynamic and dynamic critical behavior observed in closed and open systems. Dynamics and thermodynamics of the van der Waals gas provides an illustration.

35 pages

Country
Canada
Related Organizations
Keywords

thermodynamics, Statistical Mechanics (cond-mat.stat-mech), Partial differential equations of mathematical physics and other areas of application, Classical thermodynamics, heat transfer, FOS: Physical sciences, Mathematical Physics (math-ph), Onsager's variation principle, van der Waals gas, Condensed Matter - Statistical Mechanics, Mathematical Physics, Time-dependent statistical mechanics (dynamic and nonequilibrium), gradient and Hamiltonian dynamics

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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Top 10%
Average
Average
Green