
arXiv: 2310.15370
Approach of mesoscopic state variables to time independent equilibrium sates (zero law of thermodynamics) gives birth to the classical equilibrium thermodynamics. Approach of fluxes and forces to fixed points (equilibrium fluxes and forces) that drive reduced mesoscopic dynamics gives birth to the rate thermodynamics that is applicable to driven systems. We formulate the rate thermodynamics and dynamics, investigate its relation to the classical thermodynamics, to extensions involving more details, to the hierarchy reformulations of dynamical theories, and to the Onsager variational principle. We also compare thermodynamic and dynamic critical behavior observed in closed and open systems. Dynamics and thermodynamics of the van der Waals gas provides an illustration.
35 pages
thermodynamics, Statistical Mechanics (cond-mat.stat-mech), Partial differential equations of mathematical physics and other areas of application, Classical thermodynamics, heat transfer, FOS: Physical sciences, Mathematical Physics (math-ph), Onsager's variation principle, van der Waals gas, Condensed Matter - Statistical Mechanics, Mathematical Physics, Time-dependent statistical mechanics (dynamic and nonequilibrium), gradient and Hamiltonian dynamics
thermodynamics, Statistical Mechanics (cond-mat.stat-mech), Partial differential equations of mathematical physics and other areas of application, Classical thermodynamics, heat transfer, FOS: Physical sciences, Mathematical Physics (math-ph), Onsager's variation principle, van der Waals gas, Condensed Matter - Statistical Mechanics, Mathematical Physics, Time-dependent statistical mechanics (dynamic and nonequilibrium), gradient and Hamiltonian dynamics
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 2 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 10% | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
