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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Materials...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Materials Science
Article . 1989 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Materials Science
Article . 1989 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Crazing mechanisms and craze healing in glassy polymers

Authors: C. J. G. Plummer; A. M. Donald;

Crazing mechanisms and craze healing in glassy polymers

Abstract

When held at temperatures above the glass transition temperature, crazes in certain polymers may be made to heal; that is, the crazed material may be made to recover the mechanical properties it had prior to crazing. Using thin films of a variety of polymers, we have investigated whether the mechanism of entanglement loss during crazing influences the heat treatment time necessary for healing. We find that under experimental conditions for which there is evidence of disentanglement during crazing, and if the crazes do not break down, healing occurs after heat treatment times of the order of those necessary to make the craze disappear optically. Similar heat treatments applied to scission mediated crazes however, do not result in healing. We argue that scission crazing results in a high proportion of chain fragments which are unable to contribute to the entanglement network. Since the heat treatments are not sufficiently long to disperse these fragments, and hence to restore the original local entanglement density, healing does not take place. Disentanglement should not result in such damage, so, consistent with our observations, healing times should be relatively short. Hence, these results provide independent evidence for disentanglement during crazing.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
23
Average
Top 10%
Top 10%
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