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Microemulsion systems based on a C8/10 alkyl polyglucoside: A reentrant phase inversion induced by alcohols?

Authors: C. Stubenrauch; S. K. Mehta; B. Paeplow; G. H. Findenegg;

Microemulsion systems based on a C8/10 alkyl polyglucoside: A reentrant phase inversion induced by alcohols?

Abstract

The phase behavior of quaternary microemulsion systems with a technical-grade nonionic surfactant (C8/10 alkyl polyglucoside) and different medium-chain alcohols (including the monoterpene geraniol) as cosurfactants is studied at 25 °C. Contour diagrams of the three-phase body at constant oil-to-water ratio have been mapped in terms of the mass fraction variables γ (surfactant + alcohol) and δ (relative amount of alcohol in the surfactant + alcohol mixture). Significant differences in the phase behavior of systems based on the pure alkyl glucoside β-C8G1 and those with the technical-grade C8/10 APG are observed. Specifically, at high δ an anomalous shape of the three-phase region, or a second narrow three-phase region appears in systems with C8/10 APG, which is absent in systems based on β-C8G1. Whereas at δ=0.5 all systems exhibit a phase inversion 2-3-\(\bar 2\) on increasing γ, a retrograde transition 2-3-2 is observed at high δ. The anomalous shape of the three-phase body can lead to a phase sequence 2-3-\(\bar 2\)-3-2* with a reentrant 2* state, on increasing δ at constant γ. It is argued that the reentrant 2* state is due to a preferential extraction of the more lipophilic oligomers of the technical-grade surfactant into the oil phase, causing the interfacial film to become more hydrophilic again, as δ is increased.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Average
Average
Top 10%
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