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Thermodynamic characterization of metastable organic liquids at the quasi-static glass-transition-temperature

Authors: H. G. Kilian;

Thermodynamic characterization of metastable organic liquids at the quasi-static glass-transition-temperature

Abstract

Describing the metastable equilibrium states at the quasi-static glass transition temperature of organic liquids with the help of the “Frenkel model” as “voidsaturated-systems” it turns out that these states can be thermodynamically characterized by a common value of the specific excess entropy (“iso-excess-entropystate”) if an “iso-excess-volume state” at this temperature does exist. Therefore pronounced short range ordering producing the same specific entropy content of the total system should be apparent at this temperature independent of the structure of the molecules thermselves. This hypothesis can be shown to be valid for various polymer solvent mixtures too. An understanding of this general result may be related to criteria of stability of metastable quasi-static organic liquids at their temperature of glass transition.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Average
Average
Top 10%
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