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Molar mass distribution of polymers from sedimentation velocity in an analytical ultracentrifuge

Authors: M. D. Lechner; W. Mächtle;

Molar mass distribution of polymers from sedimentation velocity in an analytical ultracentrifuge

Abstract

An alternate procedure, the run time integral method, is suggested for precise determinations of molar mass distributions of polymers. The method is based on the fact that modern analytical ultracentrifuges directly measure the variable angular velocity ω as a function of time. This allows an exact calculation of the run time integral ∫ ω 2 dt and replaces the physically uncorrect zero time correction t 0 by ∫ ω 2 dt. The procedure is demonstrated by narrow and broad distributed polymers.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Average
Average
Average
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